https://doi.org/10.15255/KUI.2022.063
Published: Kem. Ind. 72 (9-10) (2023) 551–558
Paper reference number: KUI-63/2022
Paper type: Original scientific paper
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Adsorption of Diclofenac onto Activated Carbons

M. Stjepanović, K. Matanović, I. Tomac, L. Jakobek Barron and M. Habuda-Stanić

Abstract

The presence of pharmaceuticals in natural waters has been the subject of numerous studies in the last decade due to their potential negative effects on human health and the environment. Indeed, the intensive use of pharmaceuticals leads to their presence in municipal wastewater. Unfortunately, international and national regulations still do not require continuous monitoring of the presence of pharmaceuticals in natural waters and drinking water, so wastewater treatment plants do not focus on removing them from wastewater. Diclofenac, 2-[2-(2,6-dichloroanilino)phenyl]acetic acid (DCF), is a nonsteroidal compound used as an analgesic, anti-inflammatory, and antipyretic drug and is therefore commonly found in wastewater. Due to its properties, DCF remains biologically active in the aquatic environment and easily enters the food chain. Therefore, DCF should be removed from wastewater before it is discharged into water bodies. Adsorption is an efficient and simple method that can be used to remove DCF from water. In this study, the possibility of removing DCF by adsorption on activated carbon is investigated. Modified hazelnut shell (MHS), modified commercial activated carbon Cullar (MC) and unmodified commercial activated carbon Cullar (C) were batch tested as adsorbents. The tested adsorbents were characterised by FTIR, zeta potential and pH_pzc, while the adsorbent efficiency was tested in the pH range from 2 to 10 and described by isothermal studies. Among the tested adsorbents, the maximum uptake of 48.7 mg g^–1 was found when modified activated carbon Cullar was used, while both Freundlich and Langmuir isotherm models fitted well to the data. Modified activated carbon from hazelnut shells showed effective removal of DCF.

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Keywords

activated carbon, diclofenac, adsorption, water